The tables and figures below show how the boiling point changes with increasing carbon number up to C33 for different kinds of hydrocarbons, alcohols and carboxylic acids. More detailed definitions and examples of molecular structures of the different groups are given below the figures. Show
For hydrocarbons with the same carbon number the boiling point increases in the following order: multisubstituted alkane < singelsubstituted alkane < singelsubstituted alkene < normal alkene < normal alkane < alkyl cyclohexane < alkylbenzene < cycloalkene < cycloalkane < 2-, 4- and 3-alkanol / 1-alkylnaphthalene < 1-alkanol < normal alkanoic acid See also pKa values for phenols, alcohols and carboxylic acids. For full table - rotate the screen!
Definitions of organic compounds Hydrocarbon: An organic compound consisting entirely of hydrogen and carbon. Main groups of hydrocarbons: Alkane: An acyclic saturated hydrocarbon, with the general formula CnH2n+2. Also called paraffin. Alkene: An unsaturated hydrocarbon that contains at least one carbon–carbon double bond, with the general formula CnH2n. Also called olefine. Alkyne: An unsaturated hydrocarbon containing at least one carbon—carbon triple bond, with the general formula CnH2n-2. Also called acetylene. Cycloalkane: A one-ring (monocyclic) saturated hydrocarbon, with the general formula CnH2n. Also called naphthene. Cycloalkene: An alkene hydrocarbon which contains a closed ring of carbon atoms, but has no aromatic character, with the general formula CnH2n-2. Also called cycloolefin. Aromatic hydrocarbon: A cyclic (ring-shaped), planar (flat) molecule with a ring of resonance bonds that exhibits more stability than other geometric or connective arrangements with the same set of atoms. The simplest of the aromatics have 6 carbon atoms and contains 3 double bounds. A one ring aromatic without any substituents is called benzene, with the formula C6H6. Polycyclic aromatic hydrocarbons: hydrocarbon that are composed of multiple aromatic rings. A two ring aromatic without any substituents is called naphthalene, with the formula C10H8. Some under-groups of hydrocarbons given in this document: Alkyl: An alkane substituent missing one hydrogen, with general formula CnH2n+1 2-Methylalkane: A branched alkane, with a methyl group connected to the second carbon atom in the main carbon chain. 3-Methylalkane: A branched alkane, with a methyl group connected to the third carbon atom in the main carbon chain. 2-Methylalkene: A branched alkene, with a methyl group connected to the second carbon atom in the main carbon chain. Alkylcycklohexane: A monosubstituted cyclohexane with one branching via the attachment of one alkyl group on one carbon of the cyclohexane ring, with the general formula CnH(2n+1)C6H11. Alkylcycklopentane: A monosubstituted cyclopentane with one branching via the attachment of one alkyl group on one carbon of the cyclohexane ring, with the general formula CnH2n+1C5H9. Alkylbenzene: A monosubstituted benzene with one branching via the attachment of one alkyl group on one carbon of the benzene ring, with the general formula CnH(2n+1)C6H5. Alkylnaphthalene: A monosubstituted naphthalene with one branching via the attachment of one alkyl group on one carbon of one of the aromatic rings, with the general formula CnH(2n+1)C10H7. Some other groups of organic compounds: Alcohol: an organic compound in which the hydroxyl functional group (–OH) is bound to a saturated carbon atom Alkanol: An alcohol where the hydroxyl group is connected to an alkane Carboxylic acid: an organic compound that contains a carboxyl group (C(=O)OH). The general formula of a carboxylic acid is R–COOH, with R referring to the rest of the molecule. Alkanoic acid: A carboxylic acid where the R is an alkane. How does number of carbon atoms affect boiling point?Physical properties
The boiling points of alkanes increase with increasing number of carbons. This is because the intermolecular attractive forces, although individually weak, become cumulatively more significant as the number of atoms and electrons in the molecule increases.
Does carboxylic acid increase boiling point?Carboxylic acids have high boiling points compared to other substances of comparable molar mass. Boiling points increase with molar mass.
What is the cause for the high boiling points of the carboxylic acids?In a pure carboxylic acid, hydrogen bonding can occur between two molecules of acid to produce a dimer. This immediately doubles the size of the molecule and so increases the van der Waals dispersion forces between one of these dimers and its neighbors - resulting in a high boiling point.
Why does boiling point increase with carbon chain length?Melting and Boiling Point
As the carbon chain gets longer, there are more electrons in a molecule. This means that there are more (relatively) stronger intermolecular forces between the molecules. As a result, it takes more energy to break these forces, and thus the melting or boiling points increase.
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