What is the thermal conductivity of a gas?

In physics, a fluid is a substance that continually deforms (flows) under applied shear stress. Fluids are a subset of the phases of matter and include liquids, gases, plasmas, and, to some extent, plastic solids. Because the intermolecular spacing is much larger and the motion of the molecules is more random for the fluid state than for the solid-state, thermal energy transport is less effective. The thermal conductivity of gases and liquids is generally smaller than that of solids. In liquids, thermal conduction is caused by atomic or molecular diffusion. In gases, thermal conduction is caused by the diffusion of molecules from a higher energy level to a lower level.

Thermal Conductivity of Gases

What is the thermal conductivity of a gas?
The effect of temperature, pressure and chemical species on the thermal conductivity of a gas may be explained in terms of the kinetic theory of gases. Air and other gases are generally good insulators in the absence of convection. Therefore, many insulating materials (e.g., polystyrene) function simply by having a large number of gas-filled pockets, which prevent large-scale convection. Alternation of gas pocket and solid material causes heat to transfer through many interfaces, causing a rapid decrease in heat transfer coefficient.

The thermal conductivity of gases is directly proportional to the density of the gas, the mean molecular speed, and especially to the mean free path of a molecule. The mean free path also depends on the diameter of the molecule, with larger molecules more likely to experience collisions than small molecules, which is the average distance traveled by an energy carrier (a molecule) before experiencing a collision. Light gases, such as hydrogen and helium, typically have high thermal conductivity, and dense gases such as xenon and dichlorodifluoromethane have low thermal conductivity.

In general, the thermal conductivity of gases increases with increasing temperature.

Thermal Conductivity of Liquids

As was written, in liquids, the thermal conduction is caused by atomic or molecular diffusion, but physical mechanisms for explaining the thermal conductivity of liquids are not well understood. Liquids tend to have better thermal conductivity than gases, and the ability to flow makes a liquid suitable for removing excess heat from mechanical components. The heat can be removed by channeling the liquid through a heat exchanger. The coolants used in nuclear reactors include water or liquid metals, such as sodium or lead.

The thermal conductivity of nonmetallic liquids generally decreases with increasing temperature.

What is the thermal conductivity of a gas?
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Thermal conductivity is a material property that describes ability to conduct heat. Thermal conductivity can be defined as

"the quantity of heat transmitted through a unit thickness of a material - in a direction normal to a surface of unit area - due to a unit temperature gradient under steady state conditions"

Thermal conductivity units are [W/(m K)] in the SI system and [Btu/(hr ft °F)] in the Imperial system.

See also thermal conductivity variations with temperature and pressure, for:  Air,  Ammonia, Carbon Dioxide and Water

Thermal conductivity for common materials and products:

Thermal Conductivity
- k -
W/(m K)

Load Calculator!
Material/SubstanceTemperature
25 oC
(77 oF)
125 oC
(257 oF)
225 oC
(437 oF)
Acetals 0.23
Acetone 0.16
Acetylene (gas) 0.018
Acrylic 0.2
Air, atmosphere (gas) 0.0262 0.0333 0.0398
Air, elevation 10000 m 0.020
Agate 10.9
Alcohol 0.17
Alumina 36 26
Aluminum
Aluminum Brass 121
Aluminum Oxide 30
Ammonia (gas) 0.0249 0.0369 0.0528
Antimony 18.5
Apple (85.6% moisture) 0.39
Argon (gas) 0.016
Asbestos-cement board 1) 0.744
Asbestos-cement sheets 1) 0.166
Asbestos-cement 1) 2.07
Asbestos, loosely packed 1) 0.15
Asbestos mill board 1) 0.14    
Asphalt 0.75
Balsa wood 0.048
Bitumen 0.17
Bitumen/felt layers 0.5
Beef, lean (78.9 % moisture) 0.43 - 0.48
Benzene 0.16
Beryllium
Bismuth 8.1
Bitumen 0.17
Blast furnace gas (gas) 0.02
Boiler scale 1.2 - 3.5
Boron 25
Brass
Breeze block 0.10 - 0.20
Brick dense 1.31
Brick, fire 0.47
Brick, insulating 0.15
Brickwork, common (Building Brick) 0.6 -1.0
Brickwork, dense 1.6
Bromine (gas) 0.004
Bronze
Brown iron ore 0.58
Butter (15% moisture content) 0.20
Cadmium
Calcium silicate 0.05
Carbon 1.7
Carbon dioxide (gas) 0.0146    
Carbon monoxide 0.0232
Cast iron
Cellulose, cotton, wood pulp and regenerated 0.23

Cellulose acetate, molded, sheet

0.17 - 0.33
Cellulose nitrate, celluloid 0.12 - 0.21
Cement, Portland 0.29
Cement, mortar 1.73
Ceramic materials
Chalk 0.09    
Charcoal 0.084
Chlorinated poly-ether 0.13
Chlorine (gas) 0.0081
Chrome Nickel Steel 16.3    
Chromium
Chrom-oxide 0.42
Clay, dry to moist 0.15 - 1.8    
Clay, saturated 0.6 - 2.5    
Coal 0.2
Cobalt
Cod (83% moisture content) 0.54
Coke 0.184
Concrete, lightweight 0.1 - 0.3
Concrete, medium 0.4 - 0.7
Concrete, dense 1.0 - 1.8
Concrete, stone 1.7    
Constantan 23.3
Copper
Corian (ceramic filled) 1.06
Cork board 0.043
Cork, re-granulated 0.044
Cork 0.07
Cotton 0.04
Cotton wool 0.029
Carbon Steel
Cotton Wool insulation 0.029
Cupronickel 30% 30
Diamond 1000
Diatomaceous earth (Sil-o-cel) 0.06
Diatomite 0.12
Duralium
Earth, dry 1.5    
Ebonite 0.17
Emery 11.6
Engine Oil 0.15
Ethane (gas) 0.018
Ether 0.14
Ethylene (gas) 0.017
Epoxy 0.35
Ethylene glycol 0.25
Feathers 0.034
Felt insulation 0.04
Fiberglass 0.04
Fiber insulating board 0.048
Fiber hardboard 0.2    
Fire-clay brick 500oC 1.4
Fluorine (gas) 0.0254
Foam glass 0.045
Dichlorodifluoromethane R-12 (gas) 0.007    
Dichlorodifluoromethane R-12 (liquid) 0.09
Gasoline 0.15
Glass 1.05
Glass, Pearls, dry 0.18
Glass, Pearls, saturated 0.76
Glass, window 0.96    
Glass, wool Insulation 0.04
Glycerol 0.28
Gold
Granite 1.7 - 4.0
Graphite 168
Gravel 0.7
Ground or soil, very moist area 1.4
Ground or soil, moist area 1.0
Ground or soil, dry area 0.5
Ground or soil, very dry area 0.33
Gypsum board 0.17
Hairfelt 0.05    
Hardboard high density 0.15
Hardwoods (oak, maple..) 0.16
Hastelloy C 12
Helium (gas) 0.142
Honey (12.6% moisture content) 0.5
Hydrochloric acid (gas) 0.013
Hydrogen (gas) 0.168
Hydrogen sulfide (gas) 0.013
Ice (0oC, 32oF) 2.18
Inconel 15
Ingot iron 47 - 58
Insulation materials 0.035 - 0.16
Iodine 0.44
Iridium 147
Iron
Iron-oxide 0.58
Kapok insulation 0.034
Kerosene 0.15
Krypton (gas) 0.0088
Lead
Leather, dry 0.14
Limestone 1.26 - 1.33
Lithium
Magnesia insulation (85%) 0.07
Magnesite 4.15    
Magnesium
Magnesium alloy 70 - 145
Marble 2.08 - 2.94
Mercury, liquid
Methane (gas) 0.030
Methanol 0.21
Mica 0.71
Milk 0.53
Mineral wool insulation materials, wool blankets .. 0.04    
Molybdenum
Monel
Neon (gas) 0.046
Neoprene 0.05
Nickel
Nitric oxide (gas) 0.0238
Nitrogen (gas) 0.024
Nitrous oxide (gas) 0.0151
Nylon 6, Nylon 6/6 0.25
Oil, machine lubricating SAE 50 0.15
Olive oil 0.17
Oxygen (gas) 0.024
Palladium 70.9
Paper 0.05
Paraffin Wax 0.25
Peat 0.08
Perlite, atmospheric pressure 0.031    
Perlite, vacuum 0.00137    
Phenolic cast resins 0.15
Phenol-formaldehyde moulding compounds 0.13 - 0.25
Phosphorbronze 110
Pinchbeck 159
Pitch 0.13
Pit coal 0.24
Plaster light 0.2
Plaster, metal lath 0.47
Plaster, sand 0.71
Plaster, wood lath 0.28
Plasticine 0.65 - 0.8
Plastics, foamed (insulation materials) 0.03    
Platinum
Plutonium
Plywood 0.13
Polycarbonate 0.19
Polyester 0.05
Polyethylene low density, PEL 0.33
Polyethylene high density, PEH 0.42 - 0.51
Polyisoprene natural rubber 0.13
Polyisoprene hard rubber 0.16
Polymethylmethacrylate 0.17 - 0.25
Polypropylene, PP 0.1 - 0.22    
Polystyrene, expanded 0.03
Polystyrol 0.043
Polyurethane foam 0.03
Porcelain 1.5
Potassium 1
Potato, raw flesh 0.55
Propane (gas) 0.015
Polytetrafluoroethylene (PTFE) 0.25
Polyvinylchloride, PVC 0.19
Pyrex glass 1.005
Quartz mineral 3
Radon (gas) 0.0033
Red metal
Rhenium
Rhodium
Rock, solid 2 - 7    
Rock, porous volcanic (Tuff) 0.5 - 2.5    
Rock Wool insulation 0.045
Rosin 0.32
Rubber, cellular 0.045
Rubber, natural 0.13
Rubidium
Salmon (73% moisture content) 0.50
Sand, dry 0.15 - 0.25
Sand, moist 0.25 - 2    
Sand, saturated 2 - 4
Sandstone 1.7    
Sawdust 0.08
Selenium
Sheep wool 0.039
Silica aerogel 0.02    
Silicon cast resin 0.15 - 0.32
Silicon carbide 120
Silicon oil 0.1
Silver
Slag wool 0.042
Slate 2.01
Snow (temp < 0oC) 0.05 - 0.25
Sodium
Softwoods (fir, pine ..) 0.12
Soil, clay 1.1
Soil, with organic matter 0.15 - 2    
Soil, saturated 0.6 - 4    

Solder 50-50

50

Soot

0.07

Steam, saturated

0.0184
Steam, low pressure 0.0188
Steatite 2
Steel, Carbon
Steel, Stainless
Straw slab insulation, compressed 0.09
Styrofoam 0.033
Sulfur dioxide (gas) 0.0086
Sulfur, crystal 0.2
Sugars 0.087 - 0.22
Tantalum
Tar 0.19
Tellurium 4.9
Thorium
Timber, alder 0.17
Timber, ash 0.16
Timber, birch 0.14
Timber, larch 0.12
Timber, maple 0.16
Timber, oak 0.17
Timber, pitchpine 0.14
Timber, pockwood 0.19
Timber, red beech 0.14
Timber, red pine 0.15
Timber, white pine 0.15
Timber, walnut 0.15
Tin
Titanium
Tungsten
Uranium
Urethane foam 0.021    
Vacuum 0
Vermiculite granules 0.065    
Vinyl ester 0.25
Water 0.606
Water, vapor (steam) 0.0267 0.0359
Wheat flour 0.45
White metal 35 - 70
Wood across the grain, white pine 0.12
Wood across the grain, balsa 0.055
Wood across the grain, yellow pine, timber 0.147
Wood, oak 0.17    
Wool, felt 0.07
Wood wool, slab 0.1 - 0.15
Xenon (gas) 0.0051
Zinc

1) Asbestos is bad for human health when the tiny abrasive fibers are inhaled into the lungs where they can damage the lung tissue. This seems to be exacerbated by cigarette smoking and the resulting diseases are mesothelioma and lung cancer.

Example - Conductive Heat Transfer through an Aluminum Pot versus a Stainless Steel Pot

The conductive heat transfer through a pot wall can be calculated as

q = (k / s) A dT                                                (1)

or alternatively

q / A = (k / s) dT 

where 

q = heat transfer (W, Btu/h)

A = surface area (m2, ft2)

q / A = heat transfer per unit area (W/m2, Btu/(h ft2))

k = thermal conductivity  (W/mK, Btu/(hr ft °F))

dT = t1 - t2 = temperature difference (oC, oF)

s = wall thickness (m, ft)

Conductive Heat Transfer Calculator

k = thermal conductivity  (W/mK, Btu/(hr ft °F))

s = wall thickness (m, ft)

A = surface area (m2, ft2)

dT = t1 - t2 = temperature difference (oC, oF)


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Note! - that the overall heat transfer through a surface is determined by the "overall heat transfer coefficient" - which in addition to conductive heat transfer - depends on

  • Overall Heat Transfer Calculator

Conductive Heat Transfer through an Aluminum Pot Wall with thickness 2 mm - temperature difference 80oC

Thermal conductivity for aluminum is 215 W/(m K) (from the table above). Conductive heat transfer per unit area can be calculated as

 q / A = [(215 W/(m K)) / (2 10-3 m)] (80 oC) 

          = 8600000 (W/m2)

          = 8600 (kW/m2)

Conductive Heat Transfer through a Stainless Steel Pot Wall with thickness 2 mm - temperature difference 80oC

Thermal conductivity for stainless steel is 17 W/(m K) (from the table above). Conductive heat transfer per unit area can be calculated as

q / A = [(17 W/(m K)) / (2 10-3 m)] (80 oC)  

          = 680000 (W/m2)

          = 680 (kW/m2)